Materiales porosos partiendo de bloques de construcción: Del modelo a la solución de problemas mundiales
Barra lateral del artículo
Contenido principal del artículo
Resumen
Los andamiajes metal orgánicos como producto de el ensamblaje de bloques de construcción, son un ejemplo de la Química aplicada a resolver problemas globales. Aquí trataremos su historia, su definición y algunas de las aplicaciones para resolver problemas de calentamiento global, salud y escasez de agua. Esfuerzos que fueron compensados con el premio Nobel de Química.
Detalles del artículo
Citas en Dimensions Service
Citas
Batten, S. R., Champness, N. R., Chen, X.-M., Garcia-Martinez, J., Kitagawa, S., Öhrström, L., O’Keeffe, M., Suh, M. P., & Reedijk, J. (2013). Terminology of metal–organic frameworks and coordination polymers (IUPAC Recommendations 2013)*. Pure and Applied Chemistry, 85(8), 1715–1724. https://doi.org/doi:10.1351/PAC-REC-12-11-20 DOI: https://doi.org/10.1351/PAC-REC-12-11-20
Carné-Sánchez, A., Imaz, I., Cano-Sarabia, M., & Maspoch, D. (2013). A spray-drying strategy for synthesis of nanoscale metal-organic frameworks and their assembly into hollow superstructures. Nature Chemistry, 5(3), 203–211. https://doi.org/10.1038/nchem.1569 DOI: https://doi.org/10.1038/nchem.1569
Chakraborty, D., Yurdusen, A., Mouchaham, G., Nouar, F., & Serre, C. (2024). Large-Scale Production of Metal–Organic Frameworks. Advanced Functional Materials, 34(43), 1–23. https://doi.org/10.1002/adfm.202309089 DOI: https://doi.org/10.1002/adfm.202309089
Furukawa, H., Gándara, F., Zhang, Y.-B., Jiang, J., Queen, W. L., Hudson, M. R., & Yaghi, O. M. (2014). Water Adsorption in Porous Metal–Organic Frameworks and Related Materials. Journal of the American Chemical Society, 136(11), 4369–4381. https://doi.org/10.1021/ja500330a DOI: https://doi.org/10.1021/ja500330a
Furukawa, H., Ko, N., Go, Y. B., Aratani, N., Choi, S. B., Choi, E., Yazaydin, A. Ö., Snurr, R. Q., O’Keeffe, M., Kim, J., & Yaghi, O. M. (2010). Ultrahigh porosity in metal-organic frameworks. Science, 329(5990), 424–428. https://doi.org/10.1126/science.1192160 DOI: https://doi.org/10.1126/science.1192160
Ge, X., Liu, Z., Wei, N., Lin, X., & Hu, C. (2024). Microfluidic Synthesis of Defective and Hierarchical Pore Zr Metal-Organic Framework Materials and CO2 Adsorption Performance Study. Crystal Growth and Design, 24(21), 9084–9096. https://doi.org/10.1021/acs.cgd.4c01106 DOI: https://doi.org/10.1021/acs.cgd.4c01106
Horcajada, P., Chalati, T., Serre, C., Gillet, B., Sebrie, C., Baati, T., Eubank, J. F., Heurtaux, D., Clayette, P., Kreuz, C., Chang, J. S., Hwang, Y. K., Marsaud, V., Bories, P. N., Cynober, L., Gil, S., Férey, G., Couvreur, P., & Gref, R. (2010). Porous metal-organic-framework nanoscale carriers as a potential platform for drug deliveryand imaging. Nature Materials, 9(2), 172–178. https://doi.org/10.1038/nmat2608 DOI: https://doi.org/10.1038/nmat2608
Imaz, I., Rubio-Martínez, M., An, J., Solé-Font, I., Rosi, N. L., & Maspoch, D. (2011). Metal-biomolecule frameworks (MBioFs). Chemical Communications, 47(26), 7287–7302. https://doi.org/10.1039/c1cc11202c DOI: https://doi.org/10.1039/c1cc11202c
Kondo, M., Yoshitomi, T., Matsuzaka, H., Kitagawa, S., & Seki, K. (1997). Three-Dimensional Framework with Channeling Cavities for Small Molecules: {[M2(4, 4′-bpy)3(NO3)4]·xH2O}n (M Co, Ni, Zn). Angewandte Chemie International Edition in English, 36(16), 1725–1727. https://doi.org/https://doi.org/10.1002/anie.199717251 DOI: https://doi.org/10.1002/anie.199717251
McKinlay, A. C., Morris, R. E., Horcajada, P., Férey, G., Gref, R., Couvreur, P., & Serre, C. (2010). BioMOFs: Metal-organic frameworks for biological and medical applications. Angewandte Chemie - International Edition, 49(36), 6260–6266. https://doi.org/10.1002/anie.201000048 DOI: https://doi.org/10.1002/anie.201000048
Patra, S., Sene, S., Mousty, C., Serre, C., Chaussé, A., Legrand, L., & Steunou, N. (2016). Design of Laccase–Metal Organic Framework-Based Bioelectrodes for Biocatalytic Oxygen Reduction Reaction. ACS Applied Materials & Interfaces, 8(31), 20012–20022. https://doi.org/10.1021/acsami.6b05289 DOI: https://doi.org/10.1021/acsami.6b05289
Rananaware, P., Pandit, P., Narayan, M., & Brahmkhatri, V. (2025). Nanoparticle-encapsulated metal-organic frameworks: innovative design strategies and biomedical applications. Nano Trends, 11(May), 100125. https://doi.org/10.1016/j.nwnano.2025.100125 DOI: https://doi.org/10.1016/j.nwnano.2025.100125
Robson, R. (2000). A net-based approach to coordination polymers. J. Chem. Soc.{,} Dalton Trans., 21, 3735–3744. https://doi.org/10.1039/B003591M DOI: https://doi.org/10.1039/b003591m
Schneemann, A., Bon, V., Schwedler, I., Senkovska, I., Kaskel, S., & Fischer, R. A. (2014). Flexible metal–organic frameworks. Chem. Soc. Rev., 43(16), 6062–6096. https://doi.org/10.1039/C4CS00101J DOI: https://doi.org/10.1039/C4CS00101J
Song, W., Zheng, Z., Alawadhi, A. H., & Yaghi, O. M. (2023). MOF water harvester produces water from Death Valley desert air in ambient sunlight. Nature Water, 1(7), 626–634. https://doi.org/10.1038/s44221-023-00103-7 DOI: https://doi.org/10.1038/s44221-023-00103-7
Yaghi, O. M., Li, G., & Li, H. (1995). Selective binding and removal of guests in a microporous metal–organic framework. Nature, 378(6558), 703–706. https://doi.org/10.1038/378703a0 DOI: https://doi.org/10.1038/378703a0
Esta obra está bajo una licencia internacional Creative Commons Atribución-NoComercial-SinDerivadas 4.0.
Educación Química por Universidad Nacional Autónoma de México se distribuye bajo una Licencia Creative Commons Atribución-NoComercial-SinDerivar 4.0 Internacional.
Basada en una obra en http://www.revistas.unam.mx/index.php/req.